Safety Data Sheet

MATERIAL SAFETY DATA SHEET
Reg. (UE) n° 453/2010
Issued on: 14/04/1999
Rev. n°5 dated 16/09/2014
DATT CHIMICA SRL
Via Clerici 16 – 22070
Bulgarograsso (CO)
+39 031 932 551
+39031 931 287
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
Poduct name:
Product code:
DATEXAL LA
PF00031
1.2. Relevant identified uses of the substance or mixture and uses advised against
Auxiliary for dyeing process
1.3. Details of the supplier of the safety data sheet
DATT CHIMICA SRL
Nome azienda:
Via Clerici 16, 22070 Bulgarograsso (CO)
Indirizzo:
+39-031932551
Telefono:
+39-031932287
Fax:
info@dattchimica.it
E-mail:
1.4. Emergency telephone number
337-407488 Mr.Marco Amadori e-mail: marco.amadori@dattchimica.it
SECTION 2: Hazards identification.
2.1. Classification of the substance or mixture.
The product is classified as hazardous pursuant to the provisions set forth in Directives 67/548/EEC and 1999/45/EC and/or
EC
Regulation 1272/2008 (CLP) (and subsequent amendments and supplements)
Regulation 1272/2008 (CLP) and following amendments and adjustments
H318
H411
Directive 67/548/EEC and following amendments and adjustments
Xi, N, R51/53, R41
2.2. Label elements.
Hazard labelling pursuant to EC Regulation 1272/2008 (CLP) and subsequent amendments and supplements
Hazard pictograms:
Signal words:
Danger
Hazard statements:
H318
H411
Causes serious eye damage
Toxic to aquatic life with long lasting effects
Precautionary statements:
P273
P280
Avoid release to the environment.
Wear protective gloves/protective clothing/eye
protection/face protection.
P312 IF SWALLOWED: Call a POISON CENTER or
doctor/physician if you feel unwell
IF IN EYES: Rinse cautiously with water for several
minutes. Remove contact lenses, if present and easy
to do. Continue rinsing.
Immediately
call
a
POISON
CENTER
or
doctor/physician.
Dispose of contents/container to an approved waste
disposal plant.
P301 + P312
P305+P351+P338
P310
P501
Contains:
2.3. Other hazards.
---SECTION 3: Composition/information on ingredients.
3.2. Substances.
1/1
MATERIAL SAFETY DATA SHEET
Reg. (UE) n° 453/2010
Issued on: 14/04/1999
Contains:
EC:
Concentration:
EC:
INDEX:
CAS:
REACH Registration number:
Classification CE n° 1272/2008 (CLP):
Classification 1967/584/CEE:
Rev. n°5 dated 16/09/2014
DATT CHIMICA SRL
Via Clerici 16 – 22070
Bulgarograsso (CO)
+39 031 932 551
+39031 931 287
(Z)-Octadec-9-enylamine, ethoxylated (>2.5 EO)
>20%
931-965-4
26635-93-8
Not applicable (polymer)
Eye Dam. 1 H318
Aquatic Chronic 2 H411
Xi R41;
N R51/53;
SECTION 4: First aid measures.
4.1. Description of first aid measures.
Indicazioni generali:
In case of accident or if you feel unwell, seek medical advice immediately (if possible
show the label).
Contatto con gli occhi:
Wash eyes and eyelids with plenty of water.
Protect intact eye.
Contact immediately a doctor.
Contatto con la pelle:
Wash
immediately with plenty of water and acetic solution (3%) Remove
contaminated clothing. Contact immediately a doctor.
Inalazione:
Move to fresh air and keep rest Seek for medical advice
Ingestione:
Rinse with water. Do not induce vomiting. Contact immediately a doctor.
4.2. Most important symptoms and effects, both acute and delayed.
Symptoms: corrosive effects
Risks: corrosive effects
4.3. Indication of any immediate medical attention and special treatment needed.
Information not available.
SECTION 5: Firefighting measures.
5.1. Extinguishing media.
Carbon dioxide, foam, powder and nebulised water.
5.2. Special hazards arising from the substance or mixture.
In case of fire (due to decomposition): CO, (CO2) (NOx)
5.3. Advice for firefighters.
Protective clothing self-respirator (self-protector)
SECTION 6: Accidental release measures.
6.1. Personal precautions, protective equipment and emergency procedures
Wear appropriate protective clothing.
Avoid combustion source.
6.2. Environmental precautions.
Stop leak with earth or sand. Avoid the product contact rivers and sewers. If rivers, sewers, soil or vegetation are
contaminated contact competent authorities.
6.3. Methods and material for containment and cleaning up.
Use mechanical tools to collect leaked product and eliminate the remainder using jets of water. Contaminated material
should be disposed of in compliance with legislation in force
6.4. Reference to other sections.
None
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MATERIAL SAFETY DATA SHEET
Reg. (UE) n° 453/2010
Issued on: 14/04/1999
Rev. n°5 dated 16/09/2014
DATT CHIMICA SRL
Via Clerici 16 – 22070
Bulgarograsso (CO)
+39 031 932 551
+39031 931 287
SECTION 7: Handling and storage.
7.1. Precautions for safe handling.
Usual precautions for chemicals.
Avoid contact with eyes and skin. Use gloves and protect eyes/face
Keep away from ignition sources
Do not smoke
Avoid formation of aerosols
Do not drink nor eat
Provide properly ventilated place
7.2. Conditions for safe storage, including any incompatibilities.
Store away from oxidizing agents, strong acids and basis.
Keep cool and properly ventilated place
Avoid frost
Keep away from heating sources and sunlight.
Storage temperature: >50°C
Suitable containers: Stainless steel, plastic containers
German storage class (TRGS 510): 10: Combustible liquids not in Storage Class 3
7.3. Specific end use(s).
Information not available.
SECTION 8: Exposure controls/personal protection.
8.1. Control parameters.
Information not available.
8.2. Exposure controls.
Skin protection:
Hand protection:
Eyes protection:
Respiratory protection:
Protective clothing
- protection gloves against permanent contact:
Material: butyl rubber
Breakthrough time:> = 480 min
Material thickness:> = 0.7 mm
'- protection gloves against splashes:
Material: nitrile rubber / latex, nitrile
Breakthrough time:> = 30 min
Material thickness:> = 0.4mm
Protective goggles
Not required for normal use.
In case of insufficient ventilation, or limit values are exceeded in the workplace,
excessive noise or odour, in presence of aerosols, you must use a protective mask
for respiratory independent from ambient air or a protective mask respiratory
system with filter type A or a respective combined filter (presence of aerosols, mists
and smoke, eg A-P2 or ABEK-P2) in accordance with EN 141.
SECTION 9: Physical and chemical properties.
9.1. Information on basic physical and chemical properties.
a) Appearance:
b) Odour:
c) Odour threshold.:
d) pH:
e) Melting or freezing point:
f) Initial boiling point:
g) Flash point:
h) Evaporation Rate:
i) Flammability of solids and gases:
Liquid amber
Characteristic
Not available.
9-11
100-110 °C; 1.013 hPa
> 125 °C; 1.013 hPa; vaso chiuso
not applicable (liquid)
Not available.
Not available.
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MATERIAL SAFETY DATA SHEET
Reg. (UE) n° 453/2010
Issued on: 14/04/1999
Rev. n°5 dated 16/09/2014
j) Lower inflammability limit:
k) Vapour pressure.:
l) Vapour density:
m) Specific gravity:
n) Solubility:
o)
p)
q)
r)
s)
t)
DATT CHIMICA SRL
Via Clerici 16 – 22070
Bulgarograsso (CO)
+39 031 932 551
+39031 931 287
Not available.
< 0,0015 hPa; 20 °C
Not available.
Not available.
Alcohol; 20 ° C; soluble
acetone; 20 ° C; soluble
hydrocarbons; 20 ° C; negligible
Solubility in water 20 ° C; 1,013 hPa; soluble
Not available.
Not available.
Not available.
ca.70 mPa.s; 40 °C
Not explosive
Not available.
Partition coefficient: n-octanol/water:
Ignition temperature:
Decomposition temperature.:
Viscosity:
Explosive properties:
Oxidising properties:
9.2. Other information.
Not available.
SECTION 10: Stability and reactivity
10.1. Reactivity
There are no particular risks of reaction with other substances in normal conditions of use
10.2. Chemical stability
The product is stable in normal conditions of use and storage
10.3. Possibility of hazardous reactions
No hazardous reactions are foreseeable in normal conditions of use and storage.
10.4. Conditions to avoid
None in particular, however the usual precautions used for chemical products should be respected.
10.5. Incompatible materials
Information not available.
10.6. Hazardous decomposition products
In the event of thermal decomposition or fire, vapours potentially dangerous to health may be released
SECTION 11: Toxicological information
11.1. Information on toxicological effects
a) Acute toxicity
Acute oral toxicity Oleylamine, ethoxylate:
Rat LD50:> 2,000 mg / kg
Test values /self- bibliographic values
Based on the available data, the classification criteria are not met.
Acute inhalation toxicity
Oleylamine, ethoxylate:
no data available
Acute dermal
Oleylamine, ethoxylate:
no data available
b) Irritation
Skin irritation: Oleylamine, ethoxylate:
Rabbit: slightly irritating; OECD TG 404
Based on the available data, the classification criteria are not met
c) Corrosivity
Serious eye damage / eye irritation
Irritating to eyes Oleylamine, ethoxylate:
Rabbit: irritating; OECD TG 405
4/4
MATERIAL SAFETY DATA SHEET
Reg. (UE) n° 453/2010
Issued on: 14/04/1999
Rev. n°5 dated 16/09/2014
DATT CHIMICA SRL
Via Clerici 16 – 22070
Bulgarograsso (CO)
+39 031 932 551
+39031 931 287
Causes severe eye damage.
d) Sensitisation
Oleylamine, ethoxylate:
guinea pig: not sensitizing
(literature value)
Based on the available data, the classification criteria are not met
e) Reapeted dose toxicity
Teratogenicity
(STOT) – single exposure
Oleylamine, ethoxylate:
This information is not available
Oleylamine, ethoxylate:
This information is not available
Repeated dose toxicity
Oleylamine, ethoxylate:
This information is not available
Aspiration toxicity
Oleylamine, ethoxylate:
not applicable
f) Carcinogenicity
Oleylamine, ethoxylate:
This information is not available
g) Mutagenicity
In vitro Genotossicity
In vivo Genotossicity
Oleylamine, ethoxylate:
Ames test; Salmonella typhimurium; with and without metabolic activation: no
mutagenic
(literature value)
Oleylamine, ethoxylate:
This information is not available
h) Reproductive toxicity
Oleylamine, ethoxylate:
This information is not available
SECTION 12: Ecological information
12.1. Toxicity
Toxicity to fish Oleylamine, ethoxylate:
LC50 (96 h):> 1-10 mg / l; OECD TG 203
(literature value)
Toxicity to daphnia and
other aquatic invertebrates
Oleylamine, ethoxylate:
EC50 (48 h) Daphnia magna (Water flea):> 1-10 mg / l; Static test;
OECD TG 202
data are derived from evaluations or test results obtained with similar products
(conclusion by analogy).
Toxicity to aquatic plants
Oleylamine, ethoxylate:
ErC50 (72 h) Algae:> 1-10 mg / l; OECD TG 201; (literature value)
5/5
MATERIAL SAFETY DATA SHEET
Reg. (UE) n° 453/2010
Issued on: 14/04/1999
Rev. n°5 dated 16/09/2014
DATT CHIMICA SRL
Via Clerici 16 – 22070
Bulgarograsso (CO)
+39 031 932 551
+39031 931 287
12.2. Persistence and degradability
Oleylamine, ethoxylate:
Not readily biodegradable .; <60%; 28 d; aerobic; OECD TG 301 B
12.3. Bioaccumulative potential
Information not available.
12.4. Mobility in soil
Information not available.
12.5. Results of PBT and vPvB assessment
Information not available.
12.6. Other adverse effects
Unknown
SECTION 13: Disposal considerations
13.1. Waste treatment methods
Reuse, when possible. Product residues should be considered special hazardous waste. The hazard level of waste
containing this product should be evaluated according to applicable regulations.
Disposal must be performed through an authorised waste management firm, in compliance with national and local
regulations.
CONTAMINATED PACKAGING
Contaminated packaging must be recovered or disposed of in compliance with national waste management regulations.
SECTION 14: Transport information
These goods must be transported by vehicles authorized to the carriage of dangerous
goods according to the provisions set out in the current edition of the Code of
International Carriage of Dangerous Goods by Road (ADR) and in all the applicable
national regulations.
These goods must be packed in their original packagings or in packagings made of
materials resistant to their content and not reacting dangerously with it. People loading
and unloading dangerous goods must be trained on all the risks deriving from these
substances and on all actions that must be taken in case of emergency situations
14.1. UN NUMBER
ADR, RID, ADN:
IMO/IMDG:
ICAO/IATA:
3082
3082
3082
14.2. Proper Shipping Name:
ADR, RID, ADN:
IMO/IMDG:
ICAO/IATA:
HAZARDOUS MATERIAL, LIQUID, NOS (OLEYLAMINE, ETHOXYLATE)
HAZARDOUS MATERIAL, LIQUID, NOS (OLEYLAMINE, ETHOXYLATE)
HAZARDOUS MATERIAL, LIQUID, NOS (OLEYLAMINE, ETHOXYLATE)
14.3. Hazard class
ADR, RID, ADN:
IMO/IMDG:
ICAO/IATA:
9
9
9
14.4. Packing group
ADR, RID, ADN:
IMO/IMDG:
ICAO/IATA:
III
III
III
14.5. Environment hazard
Il prodotto è pericoloso per l’ambiente
14.6. Precaution
EMS:
F-A, S-F
----
6/6
MATERIAL SAFETY DATA SHEET
Reg. (UE) n° 453/2010
Issued on: 14/04/1999
Rev. n°5 dated 16/09/2014
DATT CHIMICA SRL
Via Clerici 16 – 22070
Bulgarograsso (CO)
+39 031 932 551
+39031 931 287
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Restrictions relating to the product or contained substances pursuant to Annex XVII to EC Regulation 1907/2006: None.
Substances in Candidate List (Art. 59 REACH):None.
Substances subject to authorisarion (Annex XIV REACH):None.
15.2. Chemical safety assessment
No chemical safety assessment has been processed for the mixture and the substances it contains
SECTION 16: Other information
Revisione della scheda di dati di sicurezza:
La precedente versione della scheda di dati di sicurezza è stata modificata in accordo al Regolamento (CE) n° 453/2010.
Text of hazard (H) indications mentioned in section 2-3 of the sheet:
H318
Causes serious eye damage
H411
Toxic to aquatic life with long lasting effects
R41
RISK OF SERIOUS DAMAGE TO EYES
R51/53
TOXIC TO AQUATIC ORGANISMS, MAY CAUSE LONG-TERM ADVERSE EFFECTS IN THE
AQUATIC ENVIRONMENT
GENERAL BIBLIOGRAPHY:
Directive 1967/548/CEE (and following amendments)
Directive 1999/45/CE (and following amendments)
Reg. EC Reg. n° 1272/2008 (CLP) (and following amendments)
Reg. EC Reg n° 1907/2006 (REACH) (and following amendments)
Note:
The information contained in the present sheet are based on our own knowledge on the date of the last version. Users must
verify the suitability and thoroughness of provided information according to each specific use of the product .
This document must not be regarded as a guarantee on any specific product property.
The use of this product is not subject to our direct control; therefore, users must, under their own responsibility, comply with
the current health and safety laws and regulations. The producer is relieved from any liability arising from improper uses.
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