โᚒ࣬IT࢙࣬ࣝࢠࢹࣞࢼࢠࢪ̿10 ࢻࢿ࣭࣠ࣕࢬࣝࣤ࡞ࡻࡾ᭯ᶭ࢝ࢪ ࢬࣤࢦ ᕝᏕ◂✪⛁㞹ᏄᕝᏕᑍᨯ ⚽ᒜ ⏍ࠉ᮲ཋ කబ(⚽ᒜ◂✪ᐄ) ⌦Ꮥ◂✪⛁Ꮥᑍᨯ ኬㆺ ᵫ⏠ keywords : ࢻࢿ࣭࣠ࣕࠉࢬࣝࣤࠉ᭯ᶭ࢝ࢪࢬࣤࢦ 㛜Ⓠ ┘Ⓩ ࣓ࣜࣆࢪࢬࣝࣤF8H⤎ᬏ࡛᭯ᶭ⁈፳࡛ࡡり࡞ࡻࡽ㐽ᢝⓏ࡞ᠺ㛏ࡊ࡙ᚋࡼࡿࡾ≁ᏽ ࡡࢬࣝࣤ᚜⤎ᬏ̿ࢻࢿ࣭࣠ࣕࢬࣝࣤඵ᪁ᬏ⣌࠽ࡻࡦȘ༟ᩫᬏ⣌ࡡࢬࣝࣤ㸝4:8 ࣆ࢚࣭ ࣑ࣚ 㸞̿ࡡᚺ⏕ࢅᶅ⣬ࡊ࡙࠷ࡾࠊᮇ◂✪࡚ࡢ≁࡞ࢻࢿ࣭࣠ࣕࢬࣝࣤ࡞╌┘ࡊࠉࢬࣝ ࣤ⤎ᬏࡡࡵࡗ༖ᑙమᛮ࡛᭯ᶭ࢝ࢪ࡞ᑊࡌࡾ≁㛏࠽ࡻࡦࢻࢿ࣭࣠ࣕࡡࡵࡗᵋ㏸୕ࡡฺⅤࢅ⤄ ࡲྙࢂࡎࡾࡆ࡛࡞ࡻࡽࠉᚉᮮࡡኬࡀࢦࢫ࡚ Υࡡ㐛⇍࡚⏕ࡎࡉࡾࢅ࠻࠾ࡖࡒ᭯ ᶭ࢝ࢪࢬࣤࢦ࡞ᑊࡊࠉ᩺ࡒ࡞᭯ᶭ࢝ࢪࢅ㧏វᗐ࡞᳠ฝࡊᚋ࠾ࡗᐄῺິషࡌࡾࠉᏭ౮࡚ࢤࣤࣂ ࢠࢹ࢝ࢪࢬࣤࢦࢅ⩻᱄ࡊࡒࠊ ᭯ᶭ ࢝ࢪ ࢬ ࣤࢦ ᢇ⾙ ࡡ ᴣさ ࡛≁ ᚡ ᮇ◂✪࡚⩻᱄ࡊࡒࢻࢿ࣭࣠ࣕࢬࣝࣤ 㸝ᅒ 㸞࡞ࡻࡾ᭯ᶭ࢝ࢪࢬࣤࢦࡡᴣ␆ᅒࢅᅒ㸧࡞♟ࡌࠊ ᚜⤎ᬏࢬࣝࣤࢅ㸧ࡗࡡ㞹ᴗ㛣࡞㒼⨠ࡈࡿࡒ⣪Ꮔᵋ㏸ࢅ᭯ࡌࡾ࢝ࢪࢬࣤࢦ࡚࠵ࡾࠊࢻࢿ࣠ࣕ ࣭ࢬࣝࣤࢅ㞹ᴗ㛣࡞ᣫࡳࡓࡄ࡚࠵ࡾࠉ᚜㔖࡚࠵ࡽࡼࡐࡡ㔔␒࡞ࡻࡾ᚜⣵ࡌࡀ㛣ᵋ㏸ ࢅ࢝ࢪὮ㏳࡞⏕࠷ࡾࡆ࡛࡚ࡀࡾࡆ࡛࠾ࡼࠉᚉᮮࡡ༟మ≟ࡡࡵࡡ࡞Ẓ⾪㟻✒ࢅṹ࡞✄ࡃ ࡆ࡛ྊ⬗࡛ࡽࠉ㧏វᗐ࢝ࢪࢬࣤࢦࢅᐁ⌟ࡌࡾࠊᮇ◂✪࡚⩻᱄ࡊࡒࢻࢿ࣭࣠ࣕࢬࣝࣤ ࠾ࡼࡾ᭯ᶭ࢝ࢪࢬࣤࢦࡢࠉᚉᮮࡡᢇ⾙࡞Ẓ㍉ࡊ࡙ࠉୖオࡡࡻ࠹≁ᚡࢅ᭯ࡌࡾࠊ ࢻࢿ࣭࣠ࣕࢬࣝࣤࡢࠉష⿿ᐖ᪾࡚࠵ࡾࠊ ᮞᩩᏭ౮࡚࠵ࡾࠊᚉࡖ࡙ࠉᚉᮮࡡ࢝ࢪࢬࣤࢦ࡞⏕ࡈࡿࡾ࢝ࢪវུᛮᮞᩩ࡞Ẓ࡙ࢤࢪ ࢹ࣒ࣛࢴࢹ㧏࠷ࠊ ⏕ࡌࡾᮞᩩ᚜㔖࡚࠵ࡽࡼࠉᐄῺୖ࡞࠽࠷࡙᭯ᶭ࢝ࢪฦᏄ࡛㧏វᗐ࡞ཬᚺࡌࡾࠊ ᗐࡡᙫ㡢ࢅུࡄ࡞ࡂ࠷ࠊ ᭯ᶭ࢝ࢪࡡ⛸㢦ࢅึืࡌࡾࡆ࡛ྊ⬗࡚࠵ࡾ㸝ᅒ㸨㸞ࠊୌᏽ㞹ᅸୖ࡞Ὦࡿࡾ㞹Ὦೋࡡን ࡡኬࡀࡈវུࡌࡾ᭯ᶭ࢝ࢪࡡ⛸㢦࡞ࡻࡖ࡙␏ࡾࡒࡴࠉࡐࡡንࡡኬࡀࡈࡡ㐢࠷࠾ࡼ᭯ ᶭ࢝ࢪࡡ⛸㢦ࢅึืࡌࡾࡆ࡛ྊ⬗࡚࠵ࡾࠊ 0.8 piperidine !I/I0 0.6 pyridine 0.4 ᅒ ࢻࢿ࣭࣠ࣕࢬࣝࣤࡡ 8*2 ാ toluene 0.2 benzene diethyl ether cyclohexane acetone formaldehyde ethanol methanol 0 10 20 30 40 " ᅒ ࢻࢿ࣭࣠ࣕࢬࣝࣤ࡞ࡻࡾ᭯ᶭ࢝ࢪࢬࣤࢦࡡᴣ␆ᅒ ᅒ㸨᭯ᶭ࢝ࢪࡡ⛸㢦࡛㞹Ὦንᗐ Ȝࡢࠉ᭯ᶭ⁈፳ࡡẒㄇ㞹⋙ ᚺ⏕ ࡡྊ ⬗ ᛮ ᮇᢇ⾙ࡢࠉ⣪Ꮔᛮ⬗ࡡྡྷ୕࡛ࡐࡡࢤࣤࣂࢠࢹࡡᐁ⌟ࡡྊ⬗ᛮࢅ⛆ࡴ࡙࠽ࡽࠉࢤࢪࢹࡡ ᭯ᶭ࢝ࢪ᳠ฝ⏕ࢬࣤࢦ࡛ࡊ࡙ᵕࠍ⿿ဗࡡ⤄ࡲ㎲ࡲᙽࡈࡿࡾࠊ ͤ≁セฝ㢢ࠔ᚜⤎ᬏࢬࣝࣤࢅ⏕࠷ࡒ࢝ࢪࢬ ࣤࢦࠕ㸝 ฝ㢢୯㸞 ㏻⤙ Tel:086-256-9512 Email:akiyama@ee.ous.ac.jp
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