002000028c_74.pdf

Structure Data of Free Polyatomic Molecules
404
MW
C 3H 6O
Methyl vinyl ether
Methoxyethene
Cs (anti)
(effective symmetry class)
H3C
O
CH2
The less stable conformer is effectively planar anti
with a low barrier between two gauche forms.
The threefold potential barrier to CH3 internal
rotation is determined to be V3 = 427.516(71) cm–1.
McWhorter, D.A., Cupp, S.B., Lee, C.Y., Pate, B.H.: J. Mol. Spectrosc. 193 (1999) 150.
II/25C (3, 1267)
Landolt-Börnstein
New Series II/28C