002000028b_167.pdf

Structure Data of Free Polyatomic Molecules
165
MW
CO4S
r0
Rcm
Å
3.29(5)
Carbon dioxide – sulfur dioxide (1/1)
C2v
(weakly bound complex)
(effective symmetry class)
(large-amplitude motion)
CO2 · SO2
No inversion splittings were observed in any of the isotopic
species. The C2 axis of SO2 is perpendicular to the C∞ axis
of CO2. The negative end of the SO2 dipole moment points
to the carbon atom.
Sun, L.H., Ioannou, I.I., Kuczkowski, R.L.: Mol. Phys. 88 (1996) 255.
Landolt-Börnstein
New Series II/28B