Structure Data of Free Polyatomic Molecules 313 IR N 4O 2 State υ=0 υ1=1 υ3=1 υ1=υ3=1 υ3=υtor=1 Dinitrogen monoxide dimer (weakly bound complex) Rcm [Å] a) 3.443(2) 3.416(2) 3.4287(5) 3.493(4) 3.261(2) ϕ [deg] a) φ [deg] a) 61.0(2) 61.2(3) 60.90(2) 59.2(5) 43.9(1) 0 0 0 0 29.8(2) (large-amplitude motion) NNO ⋅ NNO Symmetry C2h C2h C2h C2h C2 The geometries of the monomer subunits were assumed to be unchanged upon complexation. a ) Uncertainties were unidentified in the original paper. Hecker, A., Scheele, I., Havenith, M.: Phys. Chem. Chem. Phys. 5 (2003) 2333. See also: Qian, H.-B., Herrebout, W.A., Howard, B.J.: Mol. Phys. 91 (1997) 689. Replaces II/25A(2, 845) Landolt-Börnstein New Series II/28A
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