Structure Data of Free Polyatomic Molecules
139
MW
ClOP
a
Phosphoryl chloride
Phosphenous chloride
θ0
r0
P=O
P–Cl
Å
1.4620(105)
2.0586(44)
r∆I/∆P a)
P=O
P–Cl
Å
1.4604(28)
2.0576(8)
O=P–Cl
rs
P=O
P–Cl
Å
1.4609(5)
2.0576(1)
O=P–Cl
O=P–Cl
deg
110.04(43)
θ∆I/∆P a)
deg
110.00(17)
θs
deg
109.98(3)
Cl
P
O
) Derived by using the isotopic differences in the moments of inertia (∆I) or the planar
moments of inertia (∆P), whereas the rs is obtained from the change in moments of inertia
upon isotopic substitution, combined with the first- and second-moment conditions, if
necessary.
Brupbacher-Gatehouse, B., Brupbacher, T.: J. Chem. Phys. 111 (1999) 6300.
Landolt-Börnstein
New Series II/28A
Cs