CARRIERS LIFETIME MEASUREMENT IN POWER SILICON DEVICES BY TRIBICC C. Manfredotti, E. Vittone, F. Fizzotti, A. Logiudice, C. Paolini and P. Olivero Experimental Physics Department, University of Torino, Italy INFN, Sezione di Torino and INFN, UdR Torino, Via Giuria 1 I-101125 Torino ( Italy ) TRIBICC ( Time Resolved Ion Beam Induced Charge Collection ) represents a further improvement with respect to more traditional IBICC, since it can supply not only the charge collection efficiency ( and consequently data on mobility and trapping time of carriers in drift regions ), but also its time behaviour. At long collection times, it can supply informations about diffusion lenghts and lifetimes of carriers in the diffusion regions, which are always present in undepleted devices such as power devices. These data are of paramount importance as inputs for device simulation codes. A more general and more powerful TRIBICC method is presented in this work by using Gunn's theorem and a particular formulation of the generation function in order to solve the adjoint of the continuity equation. This method represents a strong improvement with respect to a previous one, in which lateral IBIC was used. An application of this method to a commercial power device is presented and discussed. By using microbeams, lifetime mapping by this method could be also possible. has not such constraints and which can offer a direct numerical solution in terms of charge collection efficiency. The results indicate that TRIBICC is a more powerful method with respect to IBICC and that it can be used in more general conditions. INTRODUCTION The knowledge of important parameters like minority carriers lifetime is of paramount importance not only for semiconductor materials producers, but also for computer simulation applications in which a first value, even approximate, of these parameters is needed in order to carry out device simulations. Lateral IBIC can be used and it has been used to this purpose since it probes directly the diffusion region giving very accurate results. However, in order to be applied on a finished device, it requires a time-consuming operation in order to prepare and passivate the device crosssection. TRIBICC is particularly useful in this respect, since it can be applied to a finished device without any further operation, it can work in a wide range of lifetime values ( which is a good opportunity for new materials ) and its depth of investigation can be pushed towards 100 µm ( which is a " must " for several kinds power devices ). From simulation point of view, power devices display complex geometries, with both drift and diffusion regions which can move under subsequent heat treatments and, as a consequence, they cannot be treated under simplified assumptions. Moreover, in order to analyse both IBICC and TRIBICC data, standard Ramo's theorem (1, 2 ) cannot be a good start, since it is not valid in presence of diffusion regions or, even worse, of space-charge regions driven by an external bias. In this work, we use a different approach based on Gunn's theorem which THE THEORETICAL MODEL Let us consider a closed region of volume Vol, bounded by two infinite electrodes spaced by d and maintained at constant potentials (Φ(x=0)=0,Φ(x=d)=V) by an external power supply. Inside the bounded region, there exists a semiconductor medium with dielectric constant ε and a volume charge density distribution ρ(r,t) = ρ2(r) + ρ3(r,t), where ρ2(r) is a fixed charge distribution and ρ3(r,t) is due to the mobile carriers generated at time t=0 in a certain position r=r0. In order to evaluate the charge induced by the motion of carriers, the Green’s reciprocal theorem ( 3 ) is considered. If Φ is the potential of the electromagnetic field due to the volume charge density ρ(r,t) with both the electrodes grounded and Φ’ is the potential due to the electrodes with their actual potentials in the absence of any volume charge distribution, then ∫ ρ(r,t)Φ′(r)d3r + ∫ σ(r, t)Φ′(r)ds = 0 Vol. S where σ is the surface charge density at the electrodes due to the presence of the volume charge density ρ, S is the total area of the electrodes bounding Vol. and ds is the oriented element of S. CP680, Application of Accelerators in Research and Industry: 17th Int'l. Conference, edited by J. L. Duggan and I. L. Morgan © 2003 American Institute of Physics 0-7354-0149-7/03/$20.00 351 Since Φ’ is constant at the electrodes and is given by the bias potentials and since the surface integral of σ is equal to the total charge QS at the electrodes, one gets QS = − electric field E is constant (since E=V/d), the derivative is reduced to a mere constant (dE/dV=1/d), and we get again Ramo's theorem. To evaluate the actual induced current at the electrodes, we have to calculate the following expression: 1 ρ(r, t)Φ′(r)d 3 r V ∫ Vol iS = ∫ and the induced current iS entering the electrode is: ∂ρ 3 (r, t) dQS 1 Φ′(r)d 3r =− ∫ iS = Vol ∂t dt V t t ∂E(r,V) 3 Qs (r°, t) = ∫ iSdt = ∫ ∫ j(r,t) ⋅ d rdt Vol ∂V 0 0 where the position vector r0 indicates the point where the charge is generated at time t=0. In order to interpret TRIBICC measurements by means of this equation, let us consider the generation at t=0 of Neh electron/hole pairs at x = x°. In the following we will consider a uni-dimensional model in which the coordinate x is orthogonal to the electrodes. Neh is v iS = −q d which is the usual expression of Ramo’s theorem ( 1 ). As already pointed out by Cavalleri et al. ( 2 ) the fixed space charge affects only the motion of charge carriers and is not directly involved in the expression of the induced current. In effect equal to the ratio 1 j(r, t) ⋅ E' (r)d3 r + ∫ j(r, t)d 2 s ∫ Vol S V Σ ion where Σion is the ion energy w eh and weh is the electron-hole pair creation energy (3.6 eV in silicon). Because of the short time involved in the ionization process, the charge carries are considered created all at one time (5, 6 ). The current density j flowing in the diode is given by: where E’ = − ∇Φ ′ is the electric field due to the actual potential at the electrodes in the absence of any volume charge distribution. The surface integral in the equation concerns the current entering the electrode, whereas the volume integral is relevant to the actual induced current. The above equation is the final result of the generalized Ramo’s theorem ( 2 ) and it is based on the assumption that the space charge distribution in the volume of the detector is independent of the external bias voltage, i.e. ρ2(r) does not depend from V. Such an assumption is no more valid in the case of a silicon p-n junction diode, where the space charge redistribution plays a key role in the determination of its rectifying behavior. Hence, the analysis of the charge collection process should be based on the application of the generalized Ramo-Gunn’s theorem ( 4 ). According with this theorem, the point charge q moving with the velocity v between two parallel electrodes spaced by d induces, in the external biased circuit, the following induced current iS: iS = − q ⋅ v ⋅ ∂E(r) 3 dr ∂V The induced charge is obviously obtained integrating in time the induced current evaluated in equation: If there is a single charge q generated in r0 and moving with a constant velocity v along the x axis, being ρ3(r,t) = δ(x-(x0+vt)), where δ is the Dirac’s delta distribution function and Φ’(r) = (V/d)·x, one obtains iS = Vol j(r, t) ⋅ ∂n ∂p j = q ⋅ n ⋅ µ n ⋅ E + p ⋅ µ p ⋅ E + D n ⋅ − D p ⋅ ∂x ∂x where q is the elementary charge and the excess electron (n) and hole (p) density can be evaluated by solving the relevant transport-diffusion equations with suitable boundary conditions. Such a current density is then inserted in the previous equation to get the time evolution of the induced charge generated at x0. It is worth noticing that QS(x0,t) as defined by the previous equation is the Green's function for the continuity equations. The CCE profile is then evaluated by solving a single, time dependent equation with a significant reduction of computational effort ( 7 ). An efficient method to evaluate the Green's function has been recently presented by T.H Prettyman ( 7 ). Since the excess carrier continuity equation involves linear operators, an adjoint continuity equation can be constructed: for instance, for electrons ∂n + ∂n + ∂ ∂n + n + D n − = −vn ⋅ + + G +n ∂t ∂x ∂x ∂x τ n dE (r ,V ) dV where dE/dV is the derivative of the local electric field at the point charge with respect to the bias voltage applied at the electrodes. It is worth noticing that if there is no space charge distribution in the volume, the Where the apex "+" indicates the adjoint electron concentration. The adjoint term for electrons is G n+ = + vn ⋅ 352 ∂E ∂ ∂E - D n ⋅ ∂V ∂x ∂V and vn,p = µn,p·Etot is the drift velocity for electrons and holes, respectively. It has been demonstrated ( 8 ) that the charge induced at the electrodes from the motion of electrons and holes generated at point x° at time t is given by: [ QS (x°, t) = q ⋅ n + ( x°, t ) + p + ( x°, t ) The energy loss profile Γ(x) of the protons within the sample was evaluated by the SRIM2000 simulation code ( 5 ). The output of the charge sensitive preamplifier (Canbera 1004) for each individual ion strike was digitized using a fast computer controlled Lecroy WAVERUNNER LT342 digital oscilloscope (0.5 Gsample/s). The time resolution was about 2 ns and the transient was stored in 2500 points. Fig. 2 shows the time resolved ion beam induced charge signals evaluated at three different reverse bias voltage. ] if suitable boundary and initial conditions ( Ohmic contacts at the ends and charge generation at t= 0 and x = x° . It is worth noticing that the expression of the adjoint terms differ from those described in ( 7 ) for the presence of a diffusion term which is essential for the calculation of the time evolution of the charge collection profiles in partially depleted devices. Finally, in order to compare such a model with experimental data obtained in experiments where the carrier are generated by MeV ion probes penetrating the semiconductor device through the electrode, we have to consider the contribution of the charges generated at different positions and weighted by the Bragg ( ion energy loss ) curve: RESULTS AND DISCUSSION The mathematical method described in section was used to interpret the experimental data shown in Fig. 5. The electric field and the carrier velocity profiles evaluated by the PISCESII computer code ( 9 ) were used as input parameters of the adjoint equations taking into account the dependence of the mobility from the doping concentration and electric field ( 10 ). The behavior of the hole generating functions G+n at different bias voltages are plotted in Fig. 3. R Q s (t ) = ∫ Q s ( x°, t ) ⋅ Γ ( x°) dx° 0 where Γ is the energy loss profile and R is the ion range in the semiconductor. Charge collection efficiency 1,0 EXPERIMENTAL SET-UP NA+ND The investigated sample was a commercial Mesa Rectifier Diode with the typical vertical structure ( from the top or from incoming protons direction ) p+/n/n+. The doping profile, as measured by the spreading resistance method, is shown in Fig. 1 IBICC measurements were performed at the Ruder Boskovic Institute in Zagreb (HR) using a 4 MeV proton beam. The proton flux was maintained at about 100 protons/s in order to avoid electronic pile-up, surface trapping of generated carriers and to reduce the radiation damage. 10 21 10 20 10 19 10 18 10 17 10 16 10 15 10 14 10 13 10 12 + p 100 V 0,8 0,7 0,6 0,5 50 V 0,4 0,3 0,2 0,1 0,0 0 1 2 Time (µs) 3 4 Fig. 2 - Experimental time behaviour of charge collection measurements carried out at different reverse bias voltage. Open circles: experimental data; continuous line: fitting curves + n n 200 V 0,9 The best fit of the TRIBICC data of Fig. 2 were obtained by solving the adjoint equations by means of a one-dimensional finite difference algorithm, assuming a hole bulk lifetime τ0 = (5±1) µs and a dependence of the minority carrier lifetime τ from the doping concentration given by the following phenomenological expression ( 10 ) : τ= 0 25 50 75 100 125 150 175 200 225 250 275 300 Depth (µm) τ0 NA + ND 1+ N ref where Nref is equal to 7.1 1015 cm-3 and NA,D are the acceptor and donor concentrations. Fig. 1 - Doping profile as evaluated by the spreading resistance method; NA and ND represent the acceptor and donor concentration, respectively. 353 Apart from the lifetime measurements evaluated by means of the numerical solution of the adjoint equations, some qualitative observations can be drawn from the analysis of the TRIBICC signals. The source term G+ is obviously connected with the extension of the depletion layer (DL) where carriers experience a very rapid drift. Ramo's and RamoGunn's theorems state that the charge is induced at the electrode only if the carriers move in presence of the applied electric field, i.e. only when the carriers move within the depletion layer. This means that carriers generated within the DL induce ( in less than a nanosecond ) a very short current pulse which corresponds to the sharp and intense increase of the charge collection signal. The increase of the reverse bias voltage yields an increase of the depletion layer, which corresponds to a larger amount of carriers generated within the DL and, consequently, a higher charge collected in the first nanosecond. After this short transient, the collection time is much longer. This is due to the minority carriers generating in the neutral region which diffuse towards the DL. For the above mentioned theorem, charge is induced at the electrodes only when these carriers move in presence of the electric field, i.e. only when they enter the DL; this means that their motion in the neutral region (E=0) does not yield any charge signal and the long tail in the TRIBICC signal is relevant to their arrival time at the boundary of the DL. TRIBICC is proposed as a standard method in order to evaluate minority carriers lifetime in finished devices. In the present TRIBICC version, Gunn's theorem and the adjoint equation method to solve the continuity equation is used in order to treat complex situations in which both drift and diffusion regions are present. The method introduces a generation function which better defines the depletion or drift region and gives directly the time behaviour of charge collection efficiency. The fit on experimental data is carried out with only one parameter. Preliminary results obtained on a power mesa device have been presented here : they can be shown to offer minority carriers lifetime values in agreement with expectation ones and suitable for applications in simulation of device design and behaviour Acknowledgments - Authors are particularly grateful to Dr. M. Jaksic and Z. Pastuovic of Ruder Boskovic Institute in Zagreb ( Croatia ) for help during the mesurements and for fruitful discussions. References [1] S.Ramo, Proc. of IRE 27 (1939), 584 [2] G.Cavalleri, E.Gatti, G.Fabri, V.Svelto, Nucl. Instr. and Meth. in Phys. Res. 92 (1971), 137. [3] J.D.Jackson, "Classical Electrodynamics", 2nd ed. (Wiley, New York, 1975). [4] J.B.Gunn, Solid State Electron. 7 (1964), 739. [5] J. F. Ziegler, J. P. Biersack and U. Littmark , "The Stopping and Range of Ions in Solids", Pergamon Press, New York, 1985; http://www.SRIM.org/ [6] P.A.Tove, K.Falk, Nucl. Instr. and Meth. in Phys. Res. 12 (1961), 278. [7] T.H.Prettyman, Nucl. Instr. and Meth. in Phys. Res. A 428 (1999) 72-80. [8] G.Arfken, "Mathematical methods for physicists", Academic Press, New York, 1966. [9] M.R.Pinto, C.S.Rafferty, H.R.Yeager, R.W.Dutton,"PISCES IIB", Supplementary Report, Stanford Electronics Lab., Dept. of Electrical Engineering, Standford University (1985). [10] S.Selberherr, "Analysis and Simulation of Semiconductor Devices", Springer, Vienna 1984. [11] E.Vittone, F.Fizzotti, A. Lo Giudice, C.Paolini, C.Manfredotti, Nucl. Instr. and Meth. in Phys. Res. B 161-163 (2000), 446-451. 50 V 9 2,5x10 100 V 9 2,0x10 G+p (s-1) CONCLUSIONS 200 V 9 1,5x10 9 1,0x10 8 5,0x10 0 25 50 75 100 275 300 Depth (µm) Fig. 3 - Hole generation function profile at different reverse bias voltage. 354
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