Indian Journal of Science and Technology, Vol 9(39), DOI: 10.17485/ijst/2016/v9i39/103242, October 2016 ISSN (Print) : 0974-6846 ISSN (Online) : 0974-5645 Similarity and Difference on Making Techniques of U-Shape Jar Coffins in Yeongsan River Basin, Southwestern Korea by Quantitative Analysis Chan Hee Lee1*, Ran Hee Kim1, Hong Ju Jin1 and Ji Young Lee2 Department of Cultural Heritage Conservation Science, Kongju National University, Gongju - 32588, Korea; chanlee@kongju.ac.kr, ranh@kongju.ac.kr, hj0301@kongju.ac.kr 2 Naju National Research Institute of Cultural Heritage, Korea; name01@korea.kr 1 Abstract Background/Objectives: This study is to compare the differences and commonness between the affinities of making techniques through a quantitative analysis of jar coffins in the 5th to 6th century of Yeongsan river basin. Methods/ Statistical Analysis: The only known as production site to Oryangdong have a variety of occurrences and making skills. There are composed mainly of quartz, alkali feldspar and biotite, which can be found in all jar coffins around the Najucentered consumption sites. Findings: Their firing temperature is divided into five groups, which widely vary at 700 to 1,200℃. The consumption sites were rather high with 700 to 1,150℃ while Naju-centered area. Bannam and Yeongam area showed higher range of 1,050 to 1,150℃ in firing on jar coffins. Meanwhile, jar coffin tombs in the Yeongsan river basin don’t have distinct local colors except main areas of Naju and each site shows various features. There are some differences in characteristics of jar coffin remains excavated from many tombs in the Yeongsan river basin if we look into them mainly with U-type jar coffins which are representative malformation of jar coffins excavated from production sites. Applications/Improvement: It is a little unreasonable to say that U-type large jar coffins produced in Oryangdong were widely distributed in the whole area of the Yeongsan river basin, and it is thought that they were distributed in some adjacent area. Keywords: Firing Temperature, Large Jar Coffin, Materials, Similarity and Differences, Yeongsan River Basin 1. Introduction One of the most important archaeological sciences is the utensil making techniques and provenance interpretation of source materials for ancient artifacts. Understanding such techniques is very important for tracking correctly the ancient culture and living activities. Shards from earthenware are the most common artifacts found during excavation of archeological sites. Most archaeologists have classified ancient earthenware by shapes and uses1,2. The earthenware is capable of revealing many aspects concerning an ancient culture including probable place of manufacture and the provenance of the raw materials. The mineralogical study and geochemical composition of the earthenware analysis gives a clue about the firing * Author for correspondence temperature and also yields the information about the potshards2-4. U-shape large jar coffins, one of the most important on ancient earthenware in Korean Peninsula, which can bury full-sized adult, have been excavated from the Naju area of the Yeongsan river basin in southwestern Korean. They are discriminated from other area’s jar coffins. Generally, jar coffin tombs in the area are densely distributed along the Yeongsan river system. Oryangdong site in Naju situated in midstream of the Yeongsan river is known as the only production site up to now5,6. It is generally understood that in Oryangdong during the fifth and sixth century AD, a complete U-shaped jar coffins were manufactured around the Naju area shown in Figure 1. Similarity and Difference on Making Techniques of U-Shape Jar Coffins in Yeongsan River Basin, Southwestern Korea by Quantitative Analysis Large jar coffin tombs distributed along the Yeongsan river system exist not only in Naju area of the only production sites but also in adjacent consumption sites of the Muan, Yeongam, Hampyeong and Haenam area. For this research, selection was made on representative consumption sites 25 points of U-shape jar coffins which are estimated to have been manufactured at the same time as the large jar coffins excavated from the Oryangdong remain of Naju as shown in Figure 2. Figure 2. Location map of the large jar coffin tombs around the Yeongsan river basin in southwestern Korea. Figure 1. Representative U-shaped large jar coffins around the 5th to 6th century of the Yeongsan river basin.. Most of jar coffins excluding Haenam area are distributed in 20 km radius with the Oryangdong site. According to distance from the Oryangdong site and geographical characteristics, they were classified into 3 groups as Naju-centered area, mid- and upper-stream and mid- and down-stream of the Yeongsan river system and other sites; they were also classified into jar coffin tombs in Nannam, Yeongam, Muan, Hampyeong and Haenam area in Figure 2. 2 Vol 9 (39) | October 2016 | www.indjst.org As an effort to move away from the fragmentary domains and to identify a more comprehensive and empirical properties, natural scientific approaches were employed for the studying the large jar coffins of Yeongsan river basin, but most efforts were focused on understanding the material characteristics and homogeneity of jar coffins from each remain making it difficult to understand the coffin culture of this area as a whole. Also there are high archeological and historical interests on production and distribution of large jar coffins. The most prominent belief is that large jar coffins were manufactured and distributed from Oryangdong, and the production was mostly regional. Therefore, this study conducted a quantitative analysis on physical, microscopic, mineralogical, and geochemical characteristics of large jar coffins excavated from jar coffin tombs. Materials and making techniques of excavated large jar coffins were reviewed and interpreted firing temperature and material homogeneity at the time of manufacturing through above analysis, and regional characteristics of raw materials of large jar coffins were considered through comparison with the Oryangdong jar coffins which are the only production remain in the Yeongsan river basin. Indian Journal of Science and Technology Chan Hee Lee, Ran Hee Kim, Hong Ju Jin and Ji Young LeeW 2. Occurrence and Methodology 2.1 Occurrence Jar coffin specimens from the studied sites are sandy textures whose surface patterns are differentiated by lattice pattern. While they are not stereotype in surface pattern, wall thickness and color, classification is possible, but there is no mutual connection. The jar coffins produced from the sites have a variety of surface colors including grey to greyish blue, and some of them have micro cracks and poor plasticity with matured expanding texture on the surface. The typical U-shape jar coffins as shown in Figure 1. They are broadly 16 to 78 mm thick and particularly jar coffins with 30 mm or so thickness have the biggest number in quantity. The surface patterns of the experimental jar coffin samples occurred with 8-types based on combination of lattice patterns which are divided into two patterns of rectangle-type and square-type with the scale of big (RB, SB), medium (RM, SM) and small (RS, SS) patterns, respectively. Size of each lattice shows big patterns ranged from 7 to 8 mm, medium patterns show 5 to 6 mm, and small patterns are less than 4 mm in scales, respectively, shown in Figure 3. Sometimes, the pattern less specimen and complex patterns of irregular rectangle and square are observed. Analytical samples were limited to clear property in form, and they were pieces in body with various lattice patterns, and showed diverse surface features from yellow soft quality to gray-blue hard quality. Some jar coffins of Naju main-centered areas located within 5km radius of the Oryangdong site. The wall thickness of the jar coffins in the area was about 23 to 53mm. The Bannam area, Yeonam Sijong area, Muan and Hampyeong area showed grey surface with high brightness and average about 23 mm wall thickness. Whereas, some jar coffins of Songwoldong and other sites showed 23 mm wall thickness so that we could confirm regional characteristics. 2.2 Analytical Method This research was examined similarity and difference of jar coffins from the study area to figure out material characteristics and firing temperature. First of all, physical, microscopic, mineralogical and geochemical analyses were conducted in order to determine scientific properties of jar coffin samples. For physical analysis, measurements were made with the whole Magnetic Susceptibility (SM30), chromaticity analysis (Minolta CR-300), bulk density and absorption ratio (KS L-4008). As mineralogical analysis to observe refined structure, observation was done with stereoscope (Nikon SNZ1000), polarizing microscope (Nikon Eclipse E 600W) and Scanning Electron Microscope (FE-SEM; JEOL JSM-6335F). In addition, heat characteristics of materials consisting of jar coffin were grasped with X-ray diffraction analysis (Rigaku DMAX2000) and thermal analysis (DTA-TG; 2000S, Mac Science, Co., Japan). Meantime, in order to more clearly judge material homogeneity, quantitative analysis was conducted on major elements, minor and rare earth elements using X-Ray Fluorescence Analysis (XRF), Inductively Coupled Plasma Spectrometer And Mass Spectrometer (ICP-AES, ICP-MS), and Instrumental Neutron Activation Analysis (INNA) for interpretation of geochemical behavior characteristics. 3. Result and Interpretation 3.1 Physical Property and Microtexture Physical properties of the measured large jar coffins have been divided into chromaticity analysis, whole magnetic susceptibility, bulk density and absorption Figure 3. Representative surface patterns showing large jar coffins from the Yeongsan river basin. (A) Big Rectangle (RB) type, (B) Medium Rectangle (RM) type, (C) Medium Square (SM) type, (D) Big Square (SB) type patterns, respectively. Vol 9 (39) | October 2016 | www.indjst.org Indian Journal of Science and Technology 3 Similarity and Difference on Making Techniques of U-Shape Jar Coffins in Yeongsan River Basin, Southwestern Korea by Quantitative Analysis ratio. Chromaticity analysis of jar coffins revealed that measuring ranges of a* and b* were -3.52 to 9.37 and 3.33 to 79.39, respectively, having a chromatic range as wide as visually inspected. Jar coffins from Naju area are low in redness and yellowness and display dense distribution. With the exception of coffins in Haenam, there is not clear discrepancy in chromaticity distribution from each region. Whole magnetic susceptibility measurements revealed that, with the exception of those from Jangdeung remains, most coffins were below 5 (×10-3 SI unit). Especially, the coffins found within 5km radius of Oryangdong site display abnormal distribution curve below 1 (×10-3 SI unit). Bulk density and absorption ratio measurements disclosed that ranges of Naju, and Yeongam are most extensive and similar, there are discrepancies with coffins with over 10% water absorption ratio in other areas. Alike the large jar coffins from Oryangdong site, the production remains, have simple mineral compositions with various quartz and alkali feldspar. On the violet and glaucous hard cross section of a coffin fragments are characteristic mica and micro-pores occurred during thermal denaturalization. Under the microscopy, the jar Stereoscopic Photographs Polarizing Microphotographs coffins in the other area include a large quantity of various quartz with micro crystalline and showed partly alkali feldspar and biotite as shown in Figure 4. It is presumed that the mineral sherds added to maintain the thick wall and to control the percentage of contraction during drying and firing of jar coffins, and it has contained about 11 to 20 %. Of those coffins found in remain groups in Naju including Ungokdong tombs, Bokamri and Dasidel, Hwajeongri Masan tombs and Cheongsongri tombs have similar surface textures that include stratified mica. Tombs from Nampajung, Hwajeongri Masan tombs and Cheongsongri tombs display some discrepancies. Especially, the coffins in Haenam display different textural properties with reduced content of rock fragments and increased fine particles. Under the polarizing microscope, revealed columnar white mica in coffins from Haenam. This is comparable to the content of biotite from the coffins found in Oryangdong sites shown in Figure 4. Excluding mica, mullite and hercynite influenced by high temperature firings, all samples had similar mineral contents of quartz and alkali feldspars. However, a small quantity of plagioclase was found in some coffins from Scanning Electron Micrographs Figure 4. Representative microphotographs of large jar coffin samples from the Yeongsan river basin. UGP; Ungokdong pottery, NDSP; Naju Dasidel pottery, NCSP; Naju Cheongsongri pottery, OSP; Yeongam Sinyeonri pottery, ONP; Yeongam Naedongri pottery, HOP; Haenam Wonjinri Nongam pottery, NAP; Naju Bokamri pottery, NNP; Naju Nampajung pottery, PCP; Hampyeong Cheongsuwon pottery, NCP; Naju Sinchonri pottery, MSP; Muan Sachangri pottery, OJP; Yeongam Okyari pottery. 4 Vol 9 (39) | October 2016 | www.indjst.org Indian Journal of Science and Technology Chan Hee Lee, Ran Hee Kim, Hong Ju Jin and Ji Young LeeW Bannam Yongsan tombs, Hampyeong large coffin, Naju Songweoldong coffin, and various coffins from Naju Jangdongri remains. However, thermal analysis revealed that no sample displayed DTA-TG curve and they are distinguishable depending on exothermic peak some similar overall. 3.2 Geochemistry and Firing Temperature Geochemical composition of major elements (wt.%) for large jar coffins from the Yeongsan river basin are SiO2; 55.74 to 73.99, Al2O3; 12.19 to 22.82, and Fe2O3; 2.34 to 7.00, K2O; 2.27 to 3.87, respectively. With the exception of some samples from Ungokdong, Bokamri, Dasideul and Hwajeongri Masan remains in Naju, geochemical properties of samples from each remain are almost the similar. Naju Bannam and coffin fragments from Yeongam are also generally similar with a minor difference in element components. Coffins from Muan and Hampyeong display discrepancies with sample that are similar to coffins from Naju main remains. Coffin samples from Naju Songweoldong, Jangdong and Haenam remains display somewhat different properties to samples from other areas, but coffins from the same remain have similar behavior properties of compatible and incompatible elements. This is interpreted to reflect the geology of Yeongsan river basin and made from materials from weathering of the same bed rock. However, it is far-reaching to assume that the coffins from Yeongsan river system are manufactured at the same time or under the similar conditions. The firing temperature of the ancient earthen were provide basics for understanding many aspects of ancient technology such as firing and functional relationships between specific resource manufacturing combinations3,6. Their firing temperatures from the study area are divided into five groups, which widely vary at 700 to 1,200℃ as shown in Figure 5. And they share geochemically considerable homogeneity in terms of material science. Meanwhile jar coffin tombs in the Yeongsan river basin don’t have distinct local colors except main areas of Naju, and each site shows various features. Respectively, each of jar coffins in Jangdeung, Songwoldong and Jangdongri of Naju and jar coffins in Haenam areas showed clear characteristics one and another. The firing temperature of jar coffins in the Yeongsan river basin ranged from 700 to 1,200℃ and most of jar coffins unearthed from main areas of Naju, including Vol 9 (39) | October 2016 | www.indjst.org tombs in Ungokdong6,7, were coffin fragments fire in 1,050 to 1,150℃. Sample cores of jar coffins found in Bannam of Naju and Yeongam areas also had a large number of jar coffin fire in 1,050 to 1,150℃. On the other hand, no jar coffins fire in 1,050℃ or higher were found in other areas, excluding tombs in Cheongsuwon. Therefore, to determine that the large jar coffins U-shaped produced in Oryangdong site is circulated Yeongsan river basin whole area, there is some difficulty. Figure 5. Summary on firing temperatures showing large jar coffins around the Yeongsan river basin. (A, B, C) Firing temperature groups of jar coffins by area, analysis year and type of the Oryangdong. (D, E) Grouping of firing temperature for jar coffin sites of Yeongsan river basin. SS; small square type, SM; medium square type, SB; big square type, RS; small rectangle type, RM; medium rectangle type, RB; big rectangle type, R&S; irregular rectangle and square type. 4. Concluding Remarks The Naju main-centered remains classified into the Oryangdong production remains of the large jar coffin Indian Journal of Science and Technology 5 Similarity and Difference on Making Techniques of U-Shape Jar Coffins in Yeongsan River Basin, Southwestern Korea by Quantitative Analysis and the adjacent consumption remains had a lot of selected samples, and therefore they had wide physical characteristics between the samples, but they shared almost same material characteristics due to considerable containing of stratiform mica in about 1mm except some samples. Bannam area group commonly has unclear and irregular material characteristics, but it was geochemically very similar except clayey jar coffin pieces of Yongsan group. Other jar coffins of consumption sites in the Yeongsan river basin had material scientific clear characteristics as per remains. Jar coffins of Sinyeonri and Mansuri in Yeongam area are grey colors containing stratiform mica with thin wall and they are distinct from those in Yeongam area with brown colors in most cases. In particular, jar coffins of Mansuri has homogeneity with Naju main-centered sites. Material characteristics of jar coffins in Cheongsuwon ancient tombs of Hampyeong area were similar to those of Naju-centered sites but jar coffins in Banam sites had thin wall without stratiform mica and plagioclase was detected from some samples exhibiting difference. Stratiform mica was verified from all the jar coffin samples in Muan area in which Gusanri and Sachangri ancient tombs were located and their behavior characteristics were almost same as jar coffins in Najucentered sites but brown jar coffins with low brightness showed some difference from Naju area. Also, they displayed some deficiency in the rare earth elements. Meantime, Haenam area showed a considerable difference from the jar coffins in the Yeongsan river basin from the aspect of physical, microscopic, and mineralogical characteristics, and they had clear difference from the aspect of thin wall, chromaticity, cross section, composition muscovite and chemical composition. Firing temperature range of consumption sites in the Yeongsan river basin was rather high with 700 to 1,200℃ while Naju-centered area, Bannam and Yeongam area showed higher share of 1,050 to 1,150℃ in calcination jar coffins. Bunning jar coffins over 1,050℃ were not found in other area which shows regional differences. Overall review of this study shows that there are some differences in characteristics of jar coffins excavated from many tombs in the Yeongsan river basin if we 6 Vol 9 (39) | October 2016 | www.indjst.org look into them mainly with U-type jar coffins which are representative malformation of jar coffins excavated from production sites. It is a little unreasonable to say that U-type large jar coffins produced in Oryangdong site were widely distributed in the whole area of the Yeongsan river basin and therefore, it is thought that they were distributed in some adjacent partial area. 5. Acknowledgments This study was carried out R&D Project (NRICH1407-B12F-1) supported by the Cultural Heritage Administration (National Research Institute of Cultural Heritage), Republic of Korea. 6. References 1. Ravisankar R, Kiruba S, Chandrasekaran A, Senthikumar G, Maheswaran C. Analysis of ancient potteries of Tamilnadu, India by spectroscopic techniques. Indian Journal of Science and Technology. 2010; 3(8):858-62. 2. Kim RH, Lee CH. Application of the fabrication techniques and provenances of Bronze age pottery from Seosan Sinsongri site in Midwestern Korea. International Journal of Tomography and Simulation. 2015; 28(2):85-93. 3. Ravisankar R, Kiruba S, Chandrasekaran A, Naseenrutheen A, Seran M, Balaji PD. Determination of firing temperature of some ancient potteries of Tamli Nadu, India by FT-IR spectroscopic technique. Indian Journal of Science and Technology. 2010; 3(9):1016-9. 4. Lee CH, Jin HJ, Choi JS, Na GJ. Interpretation on making techniques of some ancient ceramic artifacts from Midwestern Korean peninsula: Preliminary study. Journal of Conservation Science. 2016; 32(2):273-91. 5. Naju National Research Institute of Cultural Heritage. Naju Oryangdong Klin II (5 to 6th Century) Excavation Report. 2014. p. 25-138. 6. Jin HJ, Lee CH, Kim RH, Lee JL. Formation and composition of the 5th to 6th century Korean jar coffins from the northern slope in Naju Oryangdong site. International Journal of Applied Engineering Research. 2015; 10(90):710. 7. Kim RH, Cho MS, Yeon U, Seo JS, Lee CH. Interpretation of material homogeneity and making techniques of the jar coffins from the Oryangdong kiln site and the Ungokdong tomb site in Naju, Korea. 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