Spring 2014 (Kotz, 7th Ed)

Chemistry 1403
CRN: 10022
General Chemistry II
Spring 2014
SECTION: 40
Instructor:
Dr. Robert E. Belford
Office: SCLB 277
Email: rebelford@ualr.edu
WEB PAGE: www.ualr.edu/rebelford
Office Phone: 569-8824
Lecture:
M,W 6:00-7:15 PM, FH 102
Text:
Chemistry& Chemical Reactivity, 7th ed., Kotz, Treichel &
Townsend, Thomson Books Brooks/Cole, 2009.
Handouts in Class
Office Hours:
M,W,F: 9:00-9:50 AM
and by appointment
I will try and hold open office hours and you are welcome to drop by anytime. My office
is around the corner from the SCLB 263 departmental computing lab, and if I am busy
you can let me know you need help and then go study in the computing lab. I'll drop by
as soon as I am free.
Chemistry Computer Laboratory: SCLB 263 This is an open computer lab where you
can access any of the WEB based assignments and tutorials.
Tutoring:
To be announced
Class Bulletin Board: Outside SCLB 277 keys to exams and quizzes will be posted.
Attendance: Attendance is required. There will be announced and unannounced
quizzes. Absence during a quiz equates to a zero score. If you miss three labs periods,
you get an F for this course (see lab syllabus).
Lecture:
Read the text assignments before the class period. The lecture will be
used to cover expected competencies with respect to the subject material and should
provide an efficient study guide. Coming to lecture is necessary, but not sufficient with
respect to getting a passing grade. You must study outside of lecture.
1
Grade Calculation:
Attendance
4 Exams & Quizzes
Comprehensive Final
Lab
Total
Final grade Distributions:
05 pts
50 pts
20 pts
25 pts
100 pts
90-100 pts
80-89 pts
70-79 pts
60-69 pts
0 - 59 pts
A
B
C
D
F
There will be NO MAKEUP EXAMS or QUIZZES. If your final exam score (on a
100% basis) is higher than your lowest exam, its grade will be substituted for that grade.
In the event that you miss an exam, that exam will be considered your lowest exam score
and your final will be substituted for that grade. All quizzes and exams will be closed
book and closed notes. You will not be allowed to use programmable calculators and
students may not share calculators during quizzes or exams. Cell Phones must be
turned off and out-of-sight during exams. Cheating is strictly forbidden.
The last day to withdraw from this course is April 16.
Final Exam is 8:00-10:00 AM Wednesday, May 9
Your success in this class is important to me, and it is the policy and practice of the
University of Arkansas at Little Rock to create inclusive learning environments
consistent with federal and state law. If you have a documented disability (or need to
have a disability documented), and need an accommodation, please contact me privately
as soon as possible, so that we can discuss with the Disability Resource Center (DRC)
how to meet your specific needs and the requirements of the course. The DRC offers
resources and coordinates reasonable accommodations for students with disabilities.
Reasonable accommodations are established through an interactive process among you,
your instructor(s) and the DRC. Thus, if you have a disability, please contact me and/or
the DRC, at 501-569-3143 (V/TTY) or 501-683-7629 (VP). For more information, please
visit the DRC website at www.ualr.edu/disability.
2
Chem 1403
Date
Jan
Feb
_
_
_
April
Tentative Lecture Schedule
Spring 2012
Text & Topics
Introduction and Review 8.2-8.8, 9.2: Lewis Dot Structures, Molecular Shapes
and Molecular Polarity
15
Review: 12.1-12.4 Intermolecular Forces and Properties of Liquids
20
MLK Holiday
22
12.4: Finish chapter 12
13.1-13.2: Crystal Lattices
Plagiarism Assignment Due for Extra Credit due in class for credit
Chapter 13 1st Draft Extra Credit Definition Due by midnight Jan 22
27
13.3-13.6: Solids and Phase Diagrams
29
14.2: Solvation Processes and Henry’s Law
Chapter 14 1st Draft Definition Extra Credit Due by midnight Jan. 29
Note: 14.1 is not covered in lecture but Lab Experiment 2A
14.3-14.5: Colligative Properties and Collids
03
Review/Catchup
05
Exam 1 (Chapters 8,9,12 & 14)
Chapter 13 & 14 Final Draft Extra Credit Due by Midnight Feb 06
10
15.1-15.4: Introduction to Kinetics & Differential Rate Laws
Chapter 15 1st Draft Extra Credit Definition Due by midnight Feb. 11
12
15.4-15.5, 23.4: Integrated Rate Laws, Arrhenius Eq. & Half Lifes
17
15.5 Arrhenius Eq & Catalysts and Reaction Mechanisms
19
16.1-16.3: Equilibria, Equilibrium Constants and Reaction Quotients
Chapter 16 1st Draft Extra Credit Definition Due by midnight Feb. 19
24
16.3-16.4 Equilibrium Calculations: LeChatlier's Principle
26
16.4-16.5 More Equilibrium Calculations & Le Chatlier’s Principle
03
Exam 2(Chapters 15 & 16)
Chapter 15 & 16 Final Draft Extra Credit Due by Midnight March 4
05
17.1-17.4 Acid & Bases, pH Scale, Bronstead Lowry Acids & Bases
Chapter 17 1st Draft Definition Due by midnight Mar. 5
17.4-17-6 Acid/Base Properties of Salts, Product/Reactant Favored Systems and
_
Types of Acid/Base Reactions
10
17.7 Acid Base Calculations
12
17.8-17.9 PolyProtic Acid/Base Reactions and Lewis Acid/Bases
17.10 Acid Bases and Molecular Structure
17
18.1-2 Common Ion Effect & Buffers
Chapter 18 1st Draft Definition Due by midnight Mar. 25
19
LAST DAY TO WITHDRAW
18.3: Acid Base Titrations
24/26 Spring Break
31
18.4: Solubility of Salts
02
18.5 Precipitation Reactions
18.6 Solubility and Complex Ions
07
Exam 3 (Chapters 17 & 18)
Chapter 17 & 18 Final Draft Extra Credit Due by Midnight April 9
09
19.1-19.3 Entropy, Spontaneity and Second Law of Thermodynamics
Chapter 19 1st Draft Definition Due by midnight April 10
19.4-19.5 More Entropy, Spontaneity and Third Law of Thermodynamics
14
19.6-19.7 Gibbs Free Energy & K
16
20.1 Balancing Oxidation-Reduction Reactions
13
3
21
23
28
30
06
May
07
13
Chapter 20 1st Draft Definition Due by midnight April 17
20.2-3 Galvanic Cells
20.4 Standard Reduction Potentials
20.5-6: Electrochemistry, Thermodynamics and Nernst Eq.
20.7-20.8 Electrolysis and Stoichiometry
22.3-4: Coordination Compounds
22.4: Coordination Compounds and Isomers
Exam 4:
Chapter 17 & 18 Final Draft Extra Credit Due by Midnight May 4
23.1-23.2, 23.5 Review of Nuclear Chemistry from Gen. Chem I
FINAL EXAM (6:00-8:00 PM)
Suggested Problems from Text
(These will not be graded or collected)
Be Sure to do the Interactive Quizzes
http://www.ualr.edu/rebelford/chem1403/q1403/chem1403QP.htm
Exam 1
Chp. 8:
Chp. 9:
Chp .12:
Chp. 13:
Chp. 14:
5,7,11,17,19,21,23,27,37,39
1,3,5,7
1,5,7,11,13,15,17,19,23,25,29,39,41,43,47,49,
7,21,23,27,29,
1,3,5,7,9,11,13,15,17,19,21,23,25,27,29,31,35,37,39,41,43,45,47,51,53,55,57,
59,61,63,65,67,73,75,79
Exam 2
Chp. 15: 1,3,5,7,9,11,,13,15,17,19,21,25,,27,29,31,33,35,37,39,41,43,45,49,51,53,55,
57,59,61,63,65,75,77,79,83,
Chp. 23: 29,31,33,37,
Chp. 16: 1,3,5,7,9,11,13,15,17,19,21,23,25,27,29,31,33,37,39,41,43,45,47,49,53,55,57
Exam 3
Chp. 17: 1,3,5,7,9,11,13,15,17,19,21,23,25,27,29,31,33,35,37,39,41,43,45,47,49,51,53,
55,57,59,61,63,65,67,69,71,73,75,77,79,83,85,87,89,91,93,95,113
Chp. 18: 1,3,5,7,9,11,13,15,17,19,21,23,25,27,29,31,33,35,37,39,41,43,45,47,49,51,53,
55,59,61,63,67,69,71,73,77,79,83,85
Exam 4
Chp. 19: 1,3,5,7,15,17,19,21,25,27,27,29,31,33,35,37,,39,41,43,45,47,49,51,53,57,
61,67,69,75,79
Chp. 20: 1,3,5,7,9,13,15,17,19,21,23,25,27,29,31,33,35,37,43,45,47,49,51,53,57,59,
63,87,89
Chp. 22: 7,9,11,19,21,41
Chp. 23: 11,13,35
4